Silicon solar cells are the most broadly utilized of all solar cell due to their high photo-conversion efficiency even as single junction photovoltaic devices. Besides, the high relative abundance of silicon drives their preference in the PV landscape.
Which material is used for solar photovoltaic energy conversion?
So far, solar photovoltaic energy conversion has been used as the premium energy source in most of the orbiting satellites. Silicon has been the most used material in most of the successful photovoltaic cells. Two different forms of silicon, pure silicon and amorphous silicon are used to build the cells.
Silicon solar cells are the most broadly utilized of all solar cell due to their high photo-conversion efficiency even as single junction photovoltaic devices. Besides, the high relative abundance of silicon drives their preference in the PV landscape.
For silicon solar cells, the basic design constraints on surface reflection, carrier collection, recombination and parasitic resistances result in an optimum device of about 25% theoretical efficiency. A schematic of such an optimum device using a traditional geometry is shown below.
Silicon in photovoltaic cell: Among all of the materials listed above, silicon is the most commonly used material in the photovoltaic cells. It is also present in abundance in nature as silicon dioxide in sand and quartz, from which it is extracted by reduction with carbon. In fact, silicon accounts for about 26% of the earth's crust.
What are the different types of silicon used in photovoltaic cells?
Two different forms of silicon, pure silicon and amorphous silicon are used to build the cells. However, the use of the photovoltaic cells has been limited due to high processing cost of high purity single crystal material used and the lack of effective mass production techniques used to produce thin silicon films.
The device structure of a silicon solar cell is based on the concept of a p-n junction, for which dopant atoms such as phosphorus and boron are introduced into intrinsic silicon for preparing n- or p-type silicon, respectively. A simplified schematic cross-section of a commercial mono-crystalline silicon solar cell is shown in Fig. 2.